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1-Bromo-4-nitrobenzene
  • Chemical Name: 1-Bromo-4-nitrobenzene
  • CAS No.: 586-78-7

Factory Sells Best Quality 1-Bromo-4-nitrobenzene 586-78-7 with USP

  • Molecular Formula: C6H4BrNO2
  • Molecular Weight: 202.007
  • Appearance/Colour: light yellow powder 
  • Vapor Pressure: 0.0304mmHg at 25°C 
  • Melting Point: 124-126 °C(lit.) 
  • Refractive Index: 1.605 
  • Boiling Point: 252.635 °C at 760 mmHg 
  • Flash Point: 106.59 °C 
  • PSA: 45.82000 
  • Density: 1.719 g/cm3 
  • LogP: 2.88050 

1-Bromo-4-nitrobenzene(Cas 586-78-7) Usage

Synthesis Reference(s)

Tetrahedron, 43, p. 4321, 1987 DOI: 10.1016/S0040-4020(01)90307-2

Purification Methods

Crystallise it twice from pet ether, using charcoal before the first crystallisation. [Beilstein 5 III 619, 5 IV 729.]

InChI:InChI=1/C6H4BrNO2/c7-5-1-3-6(4-2-5)8(9)10/h1-4H

586-78-7 Relevant articles

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Bunce,Urban

, p. 821,822,823,825,826 (1971)

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Kleene

, p. 866,867 (1948)

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Ipso Nitration of Aryl Boronic Acids Using Fuming Nitric Acid

Baucom, Kyle D.,Brown, Derek B.,Caille, Seb,Murray, James I.,Quasdorf, Kyle,Silva Elipe, Maria V.

supporting information, (2021/06/30)

The ipso nitration of aryl boronic acid ...

The graphite-catalyzed: ipso -functionalization of arylboronic acids in an aqueous medium: metal-free access to phenols, anilines, nitroarenes, and haloarenes

Badgoti, Ranveer Singh,Dandia, Anshu,Parewa, Vijay,Rathore, Kuldeep S.,Saini, Pratibha,Sharma, Ruchi

, p. 18040 - 18049 (2021/05/29)

An efficient, metal-free, and sustainabl...

Selective Mild Oxidation of Anilines into Nitroarenes by Catalytic Activation of Mesoporous Frameworks Linked with Gold-Loaded Mn3O4 Nanoparticles

Armatas, Gerasimos S.,Daikopoulou, Vassiliki,Koutsouroubi, Eirini D.,Lykakis, Ioannis N.,Skliri, Euaggelia

, (2021/11/01)

This work reports the synthesis and cata...

Nitration of deactivated aromatic compounds via mechanochemical reaction

Wu, Jian-Wei,Zhang, Pu,Guo, Zhi-Xin

supporting information, (2021/05/05)

A variety of deactivated arenes were nit...

586-78-7 Process route

4-nitro-aniline
100-01-6,104810-17-5

4-nitro-aniline

4-chlorobenzonitrile
100-00-5

4-chlorobenzonitrile

para-nitrophenyl bromide
586-78-7

para-nitrophenyl bromide

Conditions
Conditions Yield
With sulfuric acid; acetic acid; Behandlung der Diazoniumsalz-Loesung mit CuCl und wss. HBr;
4-nitrophenyl 4-methylbenzenesulfonate
1153-45-3

4-nitrophenyl 4-methylbenzenesulfonate

p-nitrobenzene iodide
636-98-6

p-nitrobenzene iodide

4-chlorobenzonitrile
100-00-5

4-chlorobenzonitrile

para-nitrophenyl bromide
586-78-7

para-nitrophenyl bromide

Conditions
Conditions Yield
With dodecyltributylphosphonium iodide; at 100 ℃; Rate constant; various substituents on benzene ring and on the leaving group, in various molten phosphonium halides;

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