Home >Pharmaceutical > 1-Bromo-4-nitrobenzene
- Chemical Name: 1-Bromo-4-nitrobenzene
- CAS No.: 586-78-7
Factory Sells Best Quality 1-Bromo-4-nitrobenzene 586-78-7 with USP
- Molecular Formula: C6H4BrNO2
- Molecular Weight: 202.007
- Appearance/Colour: light yellow powder
- Vapor Pressure: 0.0304mmHg at 25°C
- Melting Point: 124-126 °C(lit.)
- Refractive Index: 1.605
- Boiling Point: 252.635 °C at 760 mmHg
- Flash Point: 106.59 °C
- PSA: 45.82000
- Density: 1.719 g/cm3
- LogP: 2.88050
1-Bromo-4-nitrobenzene(Cas 586-78-7) Usage
|
Synthesis Reference(s) |
Tetrahedron, 43, p. 4321, 1987 DOI: 10.1016/S0040-4020(01)90307-2 |
|
Purification Methods |
Crystallise it twice from pet ether, using charcoal before the first crystallisation. [Beilstein 5 III 619, 5 IV 729.] |
InChI:InChI=1/C6H4BrNO2/c7-5-1-3-6(4-2-5)8(9)10/h1-4H
586-78-7 Relevant articles
-
Bunce,Urban
, p. 821,822,823,825,826 (1971)
-
-
Kleene
, p. 866,867 (1948)
-
Ipso Nitration of Aryl Boronic Acids Using Fuming Nitric Acid
Baucom, Kyle D.,Brown, Derek B.,Caille, Seb,Murray, James I.,Quasdorf, Kyle,Silva Elipe, Maria V.
supporting information, (2021/06/30)
The ipso nitration of aryl boronic acid ...
The graphite-catalyzed: ipso -functionalization of arylboronic acids in an aqueous medium: metal-free access to phenols, anilines, nitroarenes, and haloarenes
Badgoti, Ranveer Singh,Dandia, Anshu,Parewa, Vijay,Rathore, Kuldeep S.,Saini, Pratibha,Sharma, Ruchi
, p. 18040 - 18049 (2021/05/29)
An efficient, metal-free, and sustainabl...
Selective Mild Oxidation of Anilines into Nitroarenes by Catalytic Activation of Mesoporous Frameworks Linked with Gold-Loaded Mn3O4 Nanoparticles
Armatas, Gerasimos S.,Daikopoulou, Vassiliki,Koutsouroubi, Eirini D.,Lykakis, Ioannis N.,Skliri, Euaggelia
, (2021/11/01)
This work reports the synthesis and cata...
Nitration of deactivated aromatic compounds via mechanochemical reaction
Wu, Jian-Wei,Zhang, Pu,Guo, Zhi-Xin
supporting information, (2021/05/05)
A variety of deactivated arenes were nit...
586-78-7 Process route
-
-
100-01-6,104810-17-5
4-nitro-aniline
-
-
100-00-5
4-chlorobenzonitrile
-
-
586-78-7
para-nitrophenyl bromide
| Conditions | Yield |
|---|---|
|
With
sulfuric acid; acetic acid;
Behandlung der Diazoniumsalz-Loesung mit CuCl und wss. HBr;
|
-
-
1153-45-3
4-nitrophenyl 4-methylbenzenesulfonate
-
-
636-98-6
p-nitrobenzene iodide
-
-
100-00-5
4-chlorobenzonitrile
-
-
586-78-7
para-nitrophenyl bromide
| Conditions | Yield |
|---|---|
|
With
dodecyltributylphosphonium iodide;
at 100 ℃;
Rate constant;
various substituents on benzene ring and on the leaving group, in various molten phosphonium halides;
|
586-78-7 Upstream products
-
79-21-0
peracetic acid
-
103-88-8
4-bromoacetanilide
-
108-86-1
bromobenzene
-
591-09-3
nitro acetate
586-78-7 Downstream products
-
16155-03-6
1-methyl-4-(4-nitrophenyl)piperazine
-
857436-84-1
3-methyl-6-(4-nitro-phenylsulfanyl)-pyridazine
-
6343-83-5
4-nitrophenyl(phenyl)selenide
-
79110-04-6
1-(2-((4-nitrophenyl)amino)phenyl)ethanone